原子吸收分光光度计检定最佳测试条件的选择

介绍原子吸收分光光度计检定最佳测试条件的选择技巧。     

不同热处理方式对超细粒子K—Co—Mo催化剂性能和结构的影响

以柠檬酸为络合剂,采用溶胶－凝胶法制备Co-Mo超细粒子氧化物,所得干凝胶分别置于空气和氩气中进行粒烧,然后经K2CO3助化后硫化。2使用X射线衍射（XRD）,BET比表面测试和扩展X光吸收精细结构（EXAFS）对样品进行结构表征,同时测试硫化态样品的CO加氢合成低碳混合醇活性。XRD结果表明,在空气中焙烧的样品为单一的CoMoO4物种,其晶粒尺寸约为60nm;在氩气中焙烧的样品,柠檬酸的分解对样品起到还原作用,主要物种为CoMoO3 ,同时存在少量的CoMoO4,晶粒尺寸约为20nm。BET结果表明,在氩气中焙烧的样品具有较大的比表面积。硫化态样品中主要物种为MoS2和Co9S8,此外,还可能存在CoMoS3.13物种,XRD和EXAFS结果均表明,在氩气中焙烧的样品硫化后,其晶粒尺寸相对较小,活性测试结果表明,催化剂晶粒尺寸的降低明显促进了合成醇的活性和选择性的提高。     

Vapor–Liquid Jump Conditions within a Porous Medium: Results for Mass and Energy

In this paper, we develop the mass and energy jump conditions for a vapor–liquid boundary within a porous medium. The analysis is restricted to a single fluid component and leads to the appropriate jump conditions for an evaporation front. The condition of local thermal equilibrium is assumed to exist in the homogeneous liquid and vapor regions, but not in the boundary region where rapid changes in the saturation occur.     

薄板有限元广义混合法及克服病态问题研究

以薄板理论的广义混合变分原理为基础,建立了一种适用于薄板弯曲分析的有限元广义混合模式,给出了较实用的选择分裂因子的方法,算例表明有限元广义混合法比常规位移模式的精度高,同时还能克服常规有限元中的某些病态问题。本文还讨论了该法克服常规有限元中某些病态问题的机理。     

Spatial Direct Numerical Simulation of the Large Vortical Structures in Forced Plumes

Direct numerical simulation (DNS) of forced plumes arising frominput of both momentum and buoyancy into an ambient fluid is presented.The large vortical structures in the near field of thermal and reactiveplumes are investigated. Boundary conditions associated with the spatialDNS of open-boundary buoyant flows that are compatible with the modernnon-dissipative, high-order, finite-difference schemes have beendeveloped. The governing equations for flow and combustion at the plumecenterline are put into a special form to circumvent the singularity atthe axis associated with the cylindrical coordinates. Mixing is found tobe stronger in the planar thermal plume than in the axisymmetric case.An explanation is provided based on the vorticity budget. Axisymmetricreactive plumes with a one-step reaction governed by the Arrheniuskinetics have also been studied. The unsteady effects of chemical heatrelease and combustion-induced buoyancy on the flow structures areinvestigated. Budgets of the vorticity transport are examined to revealthe mechanisms leading to the formation and evolution of large vorticalstructures in forced plumes. It is found that volumetric expansion dueto chemical heat release tends to destroy vorticity, whilecombustion-induced buoyancy under the gravitational effect generatesvorticity. The gravitational term in the vorticity transport equation isfound to be the main mechanism for the buoyant flow instability and thedevelopment of counter-rotating vortices in reactive plumes.     

Extension of the Ahiezer–Kac Determinant Formula to the Case of Real-Valued Symbols with Two Real Zeros

The Fredholm determinant asymptotics for self-adjoint convolution operators on finite intervals with real symbols vanishing on the real axis is studied. Explicit formulae are obtained in the case where the symbol satisfies the generalized zero index condition and has only two simple zeros of analytic type. These formulae are direct extensions of the Ahiezer–Kac–Szegö limit theorem which, in particular, take into account the oscillating character of the asymptotics.     

A novel finite element model for helical springs

A general and accurate finite element model for helical springs subject to axial loads (extension or/and torsion) is developed in this paper. Due to the establishment of precise boundary conditions, only a slice of the wire cross-section needs to be modelled; hence, more accurate results can be achieved. An example application to a circular cross-sectional spring is analysed in detail.     

抛物问题的拉格朗日乘子区域分解法

１．引言 近年来,一类新的非重叠区域分解方法一非匹配网格区域分解法,日益引起人们的广泛兴趣,并已成为当今区域分解方法研究的热门课题。这类区域分解方法的特点是：相邻子区域在公共边（或面）上的结点可以不重合,从而能解决许多传统区域分解方法不便解决的问题（如变动网格问题）．目前主要有两类方法来处理这种区域分解的强非协调性：Ｍｏｒｔａｒ无法（见［１－２］和［９－１０］）和拉格朗日乘子法（见［５］,［８］,［１１］和［１２］）．拉格朗日乘子法比Ｍｏｒｔａｒ无法有明显的优点：（１）界面变量（即拉格朗日乘子）…     

Li'enard型系统全局稳定性的充要条件

本文研究Li'enard型系统x=(h(y)-F(x)), y=-g(x)的全局稳定性问题.利用Filippov变换和一些新的方法建立了系统为全局稳定的系列充要条件.     

I.I.D.随机变量两两乘积之和的Hsu-Robbins型定理(II)

在本部分中,采用由Levy函数(4.1)所确定的值b